6:00am To Trap a Spy (1964)
Secret agents try to stop the assassination of an African leader touring the U.S.
Cast: Robert Vaughn, David McCallum, Luciana Paluzzi, Patricia Crowley Dir: Don Medford C-93 mins, TV-PG
7:45am Spy With My Face, The (1966)
Enemy agents turn one of their own into a dead ringer for Man from U.N.C.L.E. Napoleon Solo.
Cast: Robert Vaughn, Senta Berger, David McCallum, Leo G. Carroll Dir: John Newland C-86 mins, TV-PG
http://www.tcm.com/schedule/index.jsp?startDate=7/9/2009&timezone=EST&cid=N

I am sure both of these also ran the 1st time.
